Assay Method Information

Assay Name:  Biochemical Kinase Assay
Description:  First, 250 nL of compound dissolved in DMSO (100-fold of the desired concentration) was dispensed into a 384-well plate. A 12.5 μL substrate solution containing ATP (2 mM) and fluorogenic phosphorylation substrate AQT0101 (26 M for ALK and ROS, AssayQuant) or AQT0104 (26 μM for TRKB, AssayQuant) in buffer (50 mM HEPES pH 7.5, 0.0100 Brij-35, 0.5 mM EGTA, 10 mM MgCl2) was added and mixed thoroughly. Then, a 12.5 μL kinase solution containing ALK (1.5 nM, Carna, 08-518), ALK I1171N/D1203N (4 nM, SignalChem, custom-made), ROS1 (0.6 nM, Carma, 08-163), ROS1-G2032R (0.5 nM, SignalChem, R14-121BG), or TRKB-wt (1.5 nM, SignalChem, N17-11G) kinase domains in buffer (50 nM HEPES pH 7.5, 0.01% Brij-35,200 glycerol, 0.4 mg/mL BSA, 0.5 mM EGTA, and 10 mM MgCl2) was added and mixed thoroughly. The plate was sealed and read by SpectraMax Paradigm at λ=485 nm every 2 minutes for 120 minutes at 30° C. Exemplary data is given in Table 3. Initial rates of reaction (v) were calculated from the change in fluorescence intensity over time during the initial, linear portion of the reaction.
Affinity data for this assay
 

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